包山虎----中国科学院上海硅酸盐研究所

教育经历：

1980.09~1981.12 内蒙古师范大学，化学系。
1981.01~1985.07 北京师范大学，化学系。
1997.07~2003.03日本信州大学大学院,工学系研究科,获硕士,博士学位。

工作经历：

1985.07~1997.07 内蒙古师范大学，教师。
2003.04~2004.03 日本东京工业大学生命理工学研究科,博士后
2004.04~2009.11 日本产业技术综合研究所（中部）,特别研究员
2009.11~2010.10 日本,纪本电子工业株式会社,研究员
2010.10~ 今中科院上海硅酸盐研究所工业陶瓷中心,研究员

主要业绩：

今已发表八十余篇学术论文，其中七十多篇被SCI和EI收录。合作著书1部，译著2部。共申请专利25项，其中日本专利11项，国际专利4项，中国专利10项。

主要研究方向：

透明无机氧化物及其掺杂薄膜材料的光，电，催化特性研究
镁合金薄膜材料的气致变色与电致变色特性研究
WO₃-NiO基全固体薄膜材料器件研究
新型Mg合金薄膜氢传感器的研究

科研工作简介

新型Mg合金薄膜气致变色及电致变色器件研究

Mg合金薄膜表面上镀一层氢催化功能的金属，例如Pd,Pt或者这些金属的合金,在室温大气压下，通氢时Mg合金薄膜氢化而变成透明的金属氢化物，器件从高反射态（金属态）变成透明态（氢化物态）。

Mg合金薄膜气致变色原理

氢化过程：

Mg₂Ni + H ⇔ Mg₂NiH₄(茶色)

Mg + H⇔ MgH₂ （无色）

脱氢过程：

Mg₂NiH₄ + O₂  Mg₂Ni + 2H₂O

2MgH₂ + O₂  2Mg + 2H₂O

Mg合金-WO₃基全固体宽波段反射型电致变色器件

全固体宽波段反射型电致变色调光镜，是反射与透过来实现太阳光的可逆调控，打破了传统电致变色器件的吸热式调控的缺陷。镁镍合金层替代NiO_x层，作为主要的反射型调光层，它的基本结构如图一所示，由透明导电层ITO，离子储存层WO₃，离子传导层Ta₂O₅，氢催化层（Pd，Pt及其合金）及镁合金变色层（例如Mg₄Ni，MgTi_x合金等）。变色反应过程如下:

Mg（金属）+ 2H⁺ + 2e^- → MgH₂ （透明）

Mg₂Ni（金属）+ 4H⁺ + 4e^- → Mg₂NiH₄ （透明）

H_xWO₃（蓝色状态）→ WO₃ （透明）+ xH⁺ + xe^-

全固体反射型电致变色器件结构，透过率，响应时间及调节状态示意图

WO₃基全固体电致变色器件及性能

电致变色器件是器件在电场的作用下，通过导入电荷（离子或电子）从低透过率的着色状态到高透过率的消色状态之间产生的可逆变化的现象，在外观上表现为颜色态及透明态之间的可逆变化。主要有电致变色智能窗，储存器，显示器，汽车防眩后视镜，电子束印刷及传感器，及隐身伪装技术等领域的应用研究。WO₃基全固体电致变色智能窗及汽车防眩镜性能，上图为ITO/WO₃/Ta₂O₅/NiO_x/ITO全固体电致变色智能玻璃及ITO/WO₃/Ta₂O₅/NiO_x/Al反射型全固体电致变色汽车防眩镜性能指标，透射及反射光谱以及响应时间，器件尺寸100×100mm。

Glass/ITO/WO₃/Ta₂O₅/NiO_x/ITO全固体电致变色智能玻璃透明态与着色态。

无机氧化物的光电催化特性研究

利用反应磁控溅射技术，制备具有红外屏蔽性质的氧化钨薄膜，该薄膜具有较高的可见光透过率，较低的红外透过率以及紫外截止特性。通过X线光电子能谱及可变能量正电子湮没谱详细地解释了WO_3-X的红外屏蔽机理，其主要来源于氧空位缺陷带间跃迁产生的局域电子态（极化子）和+5W离子产生的表面等离子共振散射吸收所致。该氧化钨薄膜的光学性能如下图所示，具有良好的红外阻隔功能，有望在建筑节能，红外隐形等领域得到广泛应用。

这一研究成果发表在《RSC advances，5 (2015) 57757》上。

承担的科研项目：

国家自然科学基金面上项目，反射性高效率气致变色调光镜薄膜关键技术研究，负责人，2013.1-2016.12
中国科学院重点部署项目，高温度系数氧化钒材料，负责人，2012.7-2014.12
横向研究项目，无机全固体电致变色汽车防眩镜的研发，2016.01-2017.12
国家自然科学基金面上项目，二氧化钒结晶多形的可控制备，相变性能评价及应用探索的研究，主要参与者，2013.1-2016.12
国家自然科学基金，智能节能窗用VO2基多层膜结构设计及性能优化，主要参与者，2012.1-2015.12

近年发表的代表性论文

La Mao，Ning Li，Saren，Shanhu Bao*，Ping Jin, Excellent photochromic properties of an oxygen-containing yttrium hydride coated with tungsten oxide (YHx:O/WO3), Scripta Materialia, 14 (2018), 36-40
La Mao，Huaijuan Zhou，Ning Li，Yunchuan Xin，Saren，Shanhu Bao*，Ping Jin，Improved performance of Mg-Y alloy thin film switchable mirrors after coating with a superhydrophobic surface，Appl. Surf. Sci., 403（2017），23-28
Jingting Zhu，Aibin Huang，Haibin Ma，Yunxiang Chen，Sanpei Zhang，Shidong Ji， Shanhu Bao，Ping Jin，Hybrid Film of VO₂ Nanoparticles and Nickel(II)-based Ligand Exchange Thermochromic System: Excellent Optical Performance with A Temperature Responsive Colour Change，New Journal of Chemistry，2016.12.26
J.T. Zhu, A.B. Huang, H.B.Ma,S.H. Bao, S.D.Ji, and P. Jin, Solar-thermochromism of a hybrid film of VO2 nanoparticles and Co-Br-TMP complexes, RSC Advances, 6 (2016), 67396
Huaijuan Zhou，Jinhua Li，Shanhu Bao，Donghui Wang, Huanyong Liu, Ping Jin, The potential cytotoxicity and mechanism of VO2 thin films for intelligent thermochromic windows,RSC Advances, 5 (2015) 106315-106318
Huaijuan Zhou,Jinhua Li,Shanhu Bao,Jian Li,Xuanyong Liu,Ping Jin, Use of ZnO as Antireflective, Protective, Antibacterial, and Biocompatible Multifunction Nanolayer of Thermochromic VO2 Nanofilm for Intelligent Windows, Appl. Surf. Sci., 363 (2016) 532-542
Jianyun Zheng, Shanhu Bao, Xiaoli Zhang, Haibo Wu, Rongxiang Chen, Ping Jin, Pd-MgNi_x Nanospheres/Black-TiO₂ Porous Films with Highly Efficient Hydrogen Production by Near-Complete Suppression of Surface Recombination, Applied Catalysis B: Environmental, 183 (2016) 69-74
Jian-Yun Zheng, Shan-Hu Bao, Yan-Hong Lv, and Ping Jin, Activation and Enhancement of Room-Temperature Ferromagnetism in Cu-Doped Anatase TiO2 Films by Bound Magnetic Polaron and Oxygen Defects, ACS Appl. Mater. Interf.，6 (2014) 22243-2224.
Jianyun Zheng, Shanhu Bao, and Ping Jin, TiO₂(R)/VO₂(M)/TiO₂(A) multilayer films as smart window: Combination of energy-saving, antifogging and self-cleaning functions, Nano Energy, 11（2015）136-145
Jianyun Zheng, Shanhu Bao, Yu Guo, Ping Jin, TiO₂ films prepared by DC reactive magnetron sputtering at room temperature: Phase control and photocatalytic properties,Surface and Coatings Technology, 240 (2014) 293-300.
Meng Jiang, Shanhu Bao, Xun Cao, Yamei Li, Shaotang Li, Huaijuan Zhou, Hongjie Luo, Ping Jin, Improved luminous transmittance and diminished yellow color in VO₂ energy efficient smart thin films by Zn doping, Ceram. Inter., 40 (2014) 6331-6334.
Yi, Na，Bao, Shanhu，Zhou, Huaijuan，Xin, Yunchuan，Huang, Aibin，Ma, Yining，Li, Rong，Jin, Ping，Preparation of microstructure-controllable superhydrophobic polytetrafluoroethylene porous thin film by vacuum thermal-evaporation，Frontiers of Materials Science，2016.9.01，10(3)：320-327
Xiaoli Zhang, Shanhu Bao*, Xun Cao and Ping Jin, Optical switching properties of Pd-Ni thin film top-capped switchable mirrors, Frontiers Materials and Science, 9（3）(2015）227-233
Yunchuan Xin, Huaijuan Zhou, Xiaojie Ni, Ying Pan, Xiaoli Zhang, Jianyun Zheng, Shanhu Bao*, and Ping Jin, The optical properties of low infrared transmittance WO_3-x nanocrystal thin films prepared by DC magnetron sputtering under different oxygen ratios，RSC Advances, 5(2015) 57757-57763
Shanhu Bao, Xiaoli Zhang, Ping Jin, and Kazuki Yoshimura, Optical properties and switching durability of TiO₂ top-coated magnesium-nickel thin film switchable mirror, Jpn. J. Appl. Phys., 54 (2015) 045501.
Yu Guo, Shanhu Bao^*, Jianyun Zheng, Ping Jin，High sensitivity detection of hydrogen / deuterium based on palladium top-capped magnesium alloy thin films，Materials Research Innovations, 18 (2014) S601-S605.
J. Zheng, S. Bao, Y. Guo, P. Jin，Natural hydrophobicity and reversible wettability conversion of flat anatase TiO₂ thin film，ACS Appl. Mater. Interf.，6 (2014) 1351-1355.
Jianyun Zheng, Shanhu Bao, Yu Guo, and Ping Jin, Anatase TiO2 Films with Dominant {001} Facets Fabricated by Direct-Current Reactive Magnetron Sputtering at Room Temperature: Oxygen Defects and Enhanced Visible-Light Photocatalytic Behaviors, ACS Appl. Mater. Interf.，6 (2014) 5940-5946.
Huaijuan Zhou, Xun Cao, Meng Jiang, Shanhu Bao and Ping Jin, Surface plasmon resonance tunability in VO₂/Au/VO₂ thermochromic structure，Laser & Photonics Reviews, 8 (2014) 617-625.
Shanhu Bao, Yasusei Yamada, Kazuki Tajima, Ping Jin, Masahisa Okada, and Kazuki Yoshimura, Switchable mirror based on Mg–Zr–H thin films, J. Alloys Comp., 513 (2012) 495– 498
S. Bao, Y. Yamada, K. Tajima, M. Okada, and K. Yoshimura, Optical property and cycling durability of polytetrafluoroethylene top-covered and metal buffer layer inserted Mg-Ni switchable mirror, Sol. Energy Mater. Sol. cell, 93 (2009) 1642-1646.
Y. Yamada, S. Bao, K. Tajima, M. Okada, and K. Yoshimura, Optical properties of switchable mirrors based on Magnesium-calcium alloy thin films, Appl. Phys. Lett., 94 (2009) 191910.
Y. Yamada, K. Tajima, S. Bao, M. Okada, A. Roos, and K. Yoshimura, Real time characterization of hydrogenation mechanism of palladium thin films by in situ spectroscopic ellipsometry, J. Appl. Phys., 106 (2009) 013523.
K. Yoshimura, Y. Yamada, S. Bao, K. Tajima, and M. Okada, Preparation and characterization of gasochromic switchable mirror window with practical size, Sol. Energy Mater. Sol. Cell, 93 (2009) 2138-2142.
S. Bao, K. Tajima, Y. Yamada, M. Okada, and K. Yoshimura, Polytetrafluorethylene(PFTE) top-covered Mg-Ni switchable mirror thin films, Mater. Trans., 49 (2008) 1919.
S. Bao, Y. Yamada, K. Tajima, M. Okada, and K. Yoshimura, Gasochromic property of Mg-Ni switchable mirror thin films on flexible sheets, Jpn. J. Appl. Phys., 47 (2008) 7993-7997.
S. Bao, Y. Yamada, K. Tajima, M. Okada, and K. Yoshimura, Effect of sputtering conditions on response and durability of Mg-Ni switchable mirror thin films, Vacuum, 83 (2008) 486-489.
S. Bao, Y. Yamada, K. Tajima, M. Okada, P. Jin, and K. Yoshimura, Optical properties and degradation mechanism of Magnesium-Niobium thin film switchable mirrors, J. Ceram. Soc. Jpn, 116 (2008) 771.
S. Bao, Y. Yamada, M. Okada, and K. Yoshimura, Electrochromic properties of Pd capped Mg-Ni thin film switchable mirror, Electrochemistry, 76 (2008) 282.
S. Bao, K. Tajima,Y. Yamada, M. Okada, and K. Yoshimura, Metal-buffer-layer inserted switchable mirrors, Sol. Energy Mater. Sol. Cell, 92 (2008) 216.
S. Bao, K. Tajima,Y. Yamada, M. Okada, and K. Yoshimura, Magnesium-Titanium alloy thin film switchable mirrors, Sol. Energy Mater. Sol. Cell, 92 (2008) 224.
Y. Yamada, S. Bao, K. Yajima, K. Yoshimura, and A. Roos, Antidazzle effect of switchable mirrors prepared on substrates with rough surface, Sol. Energy Mater. Sol. Cell, 92 (2008) 1617-1620.
K. Tajima, Y. Yamada, S. Bao, M. Okada, and K. Yoshimura, Improved durability of all-solid-state switchable mirror based on Magnesium-Nickel thin film using aluminum buffer layer, J. Electrochem. Soc., 155 (2008) J278.
S. Bao, K. Tajima,Y. Yamada, M. Okada, and K. Yoshimura, Color-neutral switchable mirror based on Magnesium-Titanium thin films, Appl. Phys. A, 87 (4) (2007) 621.
S. Bao, Y. Yamada, M. Okada, and K. Yoshimura, Switching characteristic and cycling durability of Pd/Mg-Ni switchable mirror thin film coated with polymer, Appl. Surf. Sci., 253 (2007) 6268.
S. Bao, Y. Yamada, K. Tajima, M. Okada, and K. Yoshimura, New switchable mirrors based on Magnesium-Niobium thin films, Jpn. J. Appl. Phys., 46 (2007) L15.
S. Bao, Y. Yamada, K. Tajima, M. Okada, and K. Yoshimura, Titanium-buffer-layer-inserted switchable mirror based on Mg-Ni alloy thin film, Jpn. J. Appl. Phys., 45 (2006) L588.
K. Yoshimura, S. Bao, Y. Yamada, and M. Okada, Optical switching property of Pd-capped Mg-Ni alloy thin films prepared by magnetron sputtering, Vacuum, 80 (2006) 684.
S. Bao, K Fujio, and T. Nomura, Effect of ionic surfactants on the oscillation frequency of one-electrode-separated piezoelectric quartz crystal modified with chitosan and its derivatives, Coll. Poly. Sci., 283 (2005) 619.
C. Mizuno, S. Bao, T. Hinoue, and T. Nomura, Adsorption behavior of metal ions onto electrode-separated piezoelectric quartz crystal modified with bovine serum albumin, Anal. Sci., 21 (2005) 281.
S. Bao, and T. Nomura, Silver-selective sensor using an electrode-separated piezoelectric quartz crystal modified with chitosan derivative, Anal. Sci., 18 (2002) 881.